Well, video memory is used to store textures while you are gaming. The higher quality you set your games on, usually the more textures there are. However, this isn't really an issue with a 5700LE because it won't be able to render at high settings anyway. So you aren't really losing any performance with getting 128MB. What matters more is the number of pixel pipelines the card has and basically the architecture of the card. The 5700LE has the best of these in the PCI slot video card category.
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AMD 64 3500+
Chaintech NF-CK804
2x512 G. Skill DDR400 Dual Channel
eVGA PCI-e 6600GT
200GB Western Digital SATA
480W Power Supply
19" Flat CRT
Windows XP Pro SP2
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