The only problem I see with this is I don't think you can actually micromanage tasks by NIC in windows. Meaning you couldn't allocate bandwidth to either subnet by application or by task. In fact, I am not even sure how well windows would even utilize this. Perhaps if you were running server since they are designed to have multiple NICs but I think any old regular OS you probably won't benefit. If any OS did I would guess it to be a linux distro.
This is just my educated guess of course though, I could be wrong.
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