If you dont know what those mean, or if you dont know much about audio, I would just leave everything at default.
Personally I find that the Game mode sounds the best with music and movies as well, however I change a few other settings when I do that.
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Desktop // Laptop
Core 2 Quad Q9550 @ 4.0GHz // Core 2 Duo P8400 2.26GHz
Asus Rampage Formula X48 // Intel PM45
ATI 4870X2 2GB GDDR5 // 512MB GDDR3 9800M GTS
4GB (2x 2GB) DDR2 940 // 4GB DDR3 800
750GB SATAII w/32MB // 200GB SATAII 7200RPM
Creative SB X-Fi Titanium Fatal1ty
SilverStone 750W +12V@60A
3DMark06: 21391 // 9179
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