I used my X-Fi with Vista Business x64 and had no real issues with it. As long as you stay with a name brand such as Creative or M-Audio, you should be fine.
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Core 2 Duo E8400 @ 3.83GHz
Gigabyte GA-P35-DS3L
ATI HD 3870 GDDR4 @ (840/2332)
4GB (2x 2GB) DDR2-850
500GB SATAII HD w/16MB
SilverStone 750W +12V@60A
3DMark06: 11593
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