Win 32 Question?

it can be anything, from currupted dlls. your program is infected. it really depends.
You can post a hijack this Log in security section to be more accurate with the matter
 
If it's a recently downloaded program, perhaps the first time you tried to load it, and you know it's legit, it's probably simply an incomplete download or something. I've had the same thing happen when I lose my internet connection for a second, or something like that.

Otherwise, it could be an infected file or something like patrick said...
 
Can you get the exact error message? It could be a few things but without knowing exactly what it says it's hard to narrow it down. Also, does it happen with any other exe files or just that one?
 
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