yes and no.
the power connectors are the are the same size for both forms, but you have to make sure that you have all the right connectors. ATX/mATX boards come with a 20 or 24 pin main connector and a 4 or 8 pin secondary. so as long as the ATX power supply has matching connectors it will work. also there are power supply with 20+4 connectors that will work with both 20 and 24 pin main connectors. also 4+4 connectors, which work with 4 and 8 pin secondary connnectors.