Windows XP has built in whats called dynamic disks and you can setup software raids with mirror, striped or spanned volumes.
Mirror raid volumes mirror whats on the first hard drive the the second.
Striped raid volumes require two hard drives of the same size and will divide the data between the two. If you use two hard drives of seperate size the raid partition will only be ad big as the smaller hard drive mulitplied times to.
Spanned raid are similar to striped except you can use any number of hard drives of any size. It combines all the hard drives to form 1 drive in windows.