Depends a lot on the system specs and how the system is used (e.g. CPU usage, etc...). Doing some calculations, though:
If we assume an average of 150W DC draw:
At 70% efficiency (that's very low for any modern PSU), this will result in a 214.3W AC draw.
At 85% efficiency (this is realistic for many 80+ PSUs), this will result in a 176.5W AC draw.
That's a difference of 37.8W.
When used 24/7, that's a difference of 37.8 * 24 * 31 / 1000 = 28.12kWh per month.
If you're paying, for example, 8c per kWh that's a difference of 28.12 * 0.08 = $2.25 per month. With those sort of differences, the higher efficiency PSU would recover the additional purchase cost fairly quickly, but PSUs with 70% efficiency aren't so common anymore.
Of course, aside from the saving in terms of your power bill, the excess power used in the PSU with lower efficiency will be converted to heat, and the PSU with higher efficiency will generally be quieter, if that's a consideration. The unit with higher efficiency may also be a newer design as well.