Its not the program you rip with that matters its the codec you are ripping (encoding) to.
As far as looking at an mp3 visually, like magicman said, audacity can open mp3 files and show you the waveform but you won't be able to tell the difference between an mp3 and an uncompressed file.
Also I'm pretty sure you won't be able to hear the difference between a 192kbps mp3 file and the original cd unless you are using an expensive set of speakers or an expensive set of headphones/earphones. This isn't to say there isn't any quality loss with an mp3 file or you can't hear the loss in quality, but without a good set of speakers/headphones/earphones that have a very good frequency response, you won't know the difference.