All video equipment in the UK is PAL. You would have to go out of your way to find multi-format TV and VCRs.
The s-video to s-video is quite straightforward as you found.
S-video to SCART I had read of problems with that so I did some checking on pinouts for s-video to SCART connectors. I found the following are typical:
s-video luminance connected to SCART pin 20 (composite video in)
s-video chrominance connected to SCART pin 15 (red video in)
In some pinouts pin20 is also shown as luminance
In some pinouts pin15 is also shown as chrominance
After a bit more digging I found that some tv sets have 2 SCART inputs
One can switch between composite and component RGB
The other can switch between composite and s-video
Your vcr is unlikely to have two SCART inputs or component RGB input. I assume that you would have to select s-video input in the vcr but if that does not work, try them all!
The vcr must have some means of switching because it is normally expecting to see composite video on pin 20 only. Not all vcrs can even accept s-video however you wire them, especially old ones. With no s-video input in the vcr, the composite video input of the vcr will be connected to the luminance (brightness/contrast) of the s-video, hence black and white picture. If that's the case you will have to use an s-video to composite adapter (cheap) and connect the composite video to the SCART connector.
Starman*