will this work for a Desktop?

Yes, but it'll run at reduced speeds as your motherboard only supports the older SATA2 standard. Nothing you can really do about that though.

It'll still run a lot faster than a regular mechanical harddrive though.
 
Mind you, the bestbuy link you posted for the 850 evo ssd, you'll still need a sata cable and quite possible a 2.5" to 3.5" ssd adapter mount. Unless your computer case has an area dedicated for 2.5" size drives. You'll still need a sata cable regardless though.
 
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